This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis. 相似文献
The Uintjiesberg kimberlite diatreme occurs within the Proterozoic Namaqua–Natal Belt, South Africa, approximately 60 km to the southwest of the Kaapvaal craton boundary. It is a group I, calcite kimberlite that has an emplacement age of 100 Ma. Major and trace element data, in combination with petrography, are used to evaluate its petrogenesis and the nature of its source region. Macrocryst phases are predominantly olivine with lesser phlogopite, with very rare garnet and Cr-rich clinopyroxene. Geochemical variation amongst the macrocrystic samples (Mg# 0.85–0.87, SiO2=27.0–29.3%, MgO=26.1–30.5%, CaO=10.9–13.5%) is shown to result from 10% to 40% entrainment and partial assimilation of peridotite xenoliths, whereas that shown by the aphanitic samples (Mg# 0.80–0.83, SiO2=19.1–23.0%, MgO=17.9–23.9%, CaO=16.5–23.7%) is consistent with 7–25% crystal fractionation of olivine and minor phlogopite. Changing trajectories on chemical variation diagrams allow postulation of a primary magma composition with 25% SiO2, 26% MgO, 2.3% Al2O3, 5%H2O, 8.6% CO2 and Mg#=0.85.
Forward melting models, assuming 0.5% melting, indicate derivation of the primary Uintjiesberg kimberlite magma from a source enriched in light rare earth elements (LREE) by 10× chondrite and heavy REE (HREE) by 0.8–2× chondrite, the latter being dependent on the proportion of residual garnet. Significant negative Rb, K, Sr, Hf and Ti anomalies present in the inferred primary magma composition are superimposed on otherwise generally smooth primitive mantle-normalized trace element patterns, and are inferred to be a characteristic of the primary magma composition. The further requirement for a source with chondritic or lower HREE abundances, residual olivine with high Fo content (Fo94) suggests derivation from a mantle previously depleted in mafic melt but subsequently enriched in highly incompatible elements prior to kimberlite genesis. These requirements are interpreted in the context of melting of continental lithospheric mantle previously enriched by metasomatic fluids derived from a sublithospheric (plume?) source. 相似文献
We have analyzed the stable oxygen isotopic composition of two Porites corals from the Chagos Archipelago, which is situated in the geographical center of the Indian Ocean. Coral δ18O at this site reliably records temporal variations in precipitation associated with the Intertropical Convergence Zone (ITCZ). Precipitation maxima occur in boreal winter, when the ITCZ forms a narrow band across the Indian Ocean. The Chagos then lies within the center of the ITCZ, and rainfall is strongly depleted in δ18O. A 120-yr coral isotopic record indicates an alternation of wet and dry intervals lasting 15 to 20 yr. The most recent 2 decades are dominated by interannual variability, which is tightly coupled to the El Niño-Southern Oscillation (ENSO). This is unprecedented in the 120 yr of coral record. As the ITCZ is governed by atmospheric dynamics, this provides evidence of a major change in the coupled ENSO-monsoon system. 相似文献
Doklady Earth Sciences - Data on the carbon isotope composition of graphite and CO2 from inclusions in quartz of granitoids of the Southern Marginal Zone (SMZ) of the Limpopo granulite belt, South... 相似文献
A number of rare phosphates have been found in specimens from the Chalotskoe pegmatite deposit, Transbaikal region, Russia: väyrynenite, MnBe[PO4](OH,F); parascholzite, CaZn2[PO4]2 · 2H2O; messelite, Ca2(Fe2+,Mn)[PO4]2 · 2H2O; eosphorite, MnAl[PO4](OH)2 · H2O; moraesite, Be2[PO4](OH)4H2O; and fluorapatite. Väyrynenite forms pink grains 2–3 mm in size, less frequent prismatic crystals up to 0.8 × 3.0 cm, and spheres up to 3 mm in diameter. Parascholzite occurs as pockets up to 0.6 × 1.0 cm composed from snow-white small grains. Messelite forms pale yellow honeycomb grains and poorly shaped crystals up to 1 mm. Eosphorite has been seen in the Chalotskoe pegmatites before, but it has not been studied in detail. It occurs as red-brown prismatic crystals up to 8 cm in length, occasionally forming openbook- like aggregates and pink to pale pink grains up to 5 mm in size. Moraesite forms snow-white fibrous aggregates up to 5 × 6 mm, together with white spheres and short prismatic crystals of fluorapatite up to 1 mm. Microcline, albite, quartz, muscovite, beryl, schorl, almandine-spessartine, columbite-(Fe), and bertrandite are associated minerals. Väyrynenite and parascholzite are found for the first time in Russia.
The scaling properties of the depth of the inner-layer of flow over low hills are studied by means of numerical solution of the equations. Two closure schemes are applied: the mixing-length model and the E- formulation. It is shown that the scale relation for the inner-layer depth lies between two formulations proposed in literature. It is also shown that the scale relation depends on the closure scheme.Presently at the European Centre for Medium-Range Weather Forecasts, Shinficld Park, Reading, Berkshire RG2 9AX, England. 相似文献
Summary It is recommended that the data from measurements with supraconducting gravity meters be also analysed with regard to verifying the gravitation absorption hypothesis. Based on theoretical data from a3-year period, the spectrum of the assumed effect of shielding the gravitational influence of the Sun by the Earth's body on the value of the acceleration of gravity has been calculated for the tidal station Brussels (Figs 2a–e).
¶rt;aam aauuam ¶rt;a uu n¶rt;uaumau ma mu u nuunm n¶rt;auaumauu. a mmuu ¶rt;a a mmu nu¶rt; u nm n¶rt;naa ma auauaumau ¶rt;mu a m a uu u u mmu ¶rt; nuu mauu (u. 2a–).
Polarized infrared absorption spectra of thin single-crystal slabs parallel to (010) and (001) of a staurolite from Pizzo Forno, Ticino, with analyzed composition (Fe2.9Mg0.9Zn0.1Mn0.1)Al17.5Ti0.1(Si7.7Al0.3)O48H3 have been measured in the range of 3000–4000 cm?1. From the pleochroitic behaviour of the OH-vibrations three groups of bands can be distinguished: the bands of group I, a strong band at 3445 cm?1 plus a weak shoulder at 3358 cm?1, and the bands of group II, a weak band centered at 3677 cm?1 plus a shoulder at 3635 cm?1, are assigned to the H1 and H2 protons, respectively. The bands of group III, a weak band at 3577 cm?1 plus a shoulder, cannot be interpreted on the basis of the proton positions known so far. We assign them to an additional proton H3, which is bonded to O1 and shows a bifurcated hydrogen bridge to two O5 in a vacant T2 site. 相似文献
Waterfowl and American coot data collected from aerial censusing on Currituck Sound were compared during three periods: before Eurasian watermilfoil (Myriophyllum spicatum) colonization (1961–1965); during Eurasian watermilfoil infestation (1968–1977); and following the near absence of submersed macrophytic vegetation after Eurasian watermilfoil decline (1981–1990). Numbers of dabbling ducks (Anas rubripes, Anas platyrhynchos, Anas acuta, Anas americana, Anas crecca), ring-necked ducks (Aythya collaris), and American coot (Fulica americana) were significantly different in Currituck Sound (p<0.05) in at least two of these periods and were highest during Eurasian watermilfoil infestation. These species also constituted higher percentages of the Atlantic Flyway counts during Eurasian watermilfoil infestation. than in periods before or after. Numbers of snow geese (Chen caerulescens), Canada geese (Branta canadensis), and canvasbacks (Aythya valisneria) were significantly different between periods; however, these birds exhibited a consistent decline from the early to the late period. This study suggests that submersed macrophytes, specifically Eurasian watermilfoil, support increased numbers of dabbling ducks, ring-necked ducks, and American coot. 相似文献
